聚乙二醇-400填充柱”
以聚乙二醇-400(PEG-400)作为固定相,涂渍在惰性固体载体上,并填充在金属或玻璃管中制成的气相色谱柱。
核心组成部分
一个完整的聚乙二醇-400填充柱由三部分构成:
柱管:通常为不锈钢或玻璃材质,长度一般在1-3米,内径2-4毫米。
载体:一种化学惰性、多孔性的固体颗粒,作用是承载固定液。常用的有:
Chromosorb W:白色硅藻土载体,惰性好,适用于极性固定液和分析极性样品。
Chromosorb P:红色硅藻土载体,吸附性稍强。
玻璃微球:非硅藻土载体,吸附性极低。
固定相:聚乙二醇-400。
PEG-400 是一种平均分子量为400的聚乙二醇,在室温下为液体。
它是一种极性的固定相,其分离机理主要基于物质与固定相之间的氢键作用力和偶极-偶极相互作用。
名称:气相色谱柱
规格:聚乙二醇400:6201担体(60-80目)20:80
型号:PEG-400/6201; 3M*3MM
编号:20251112001
zui高温度:100°C
应用:酸,醛,醇,酯,苯系物,杂醇油
适用于:
安捷伦490在线/便携,4890,5890,6890,7820,7890,8860,8890
岛津GC-14C,GC-2010,GC-2014,GC-2030
赛默飞1310,1300,1610,1600
瓦里安3800系列
布鲁克PE580,590,680,690
磐诺A90,福立GC9790,华爱,天瑞,天美,GC7900,川仪,北分瑞利,东西电子,鲁南瑞虹,捷岛/科晓
浩瀚色谱研制的PEG400填充柱的主要特点:
极性:属于中强极性固定相。
“通用型”极性柱:因其良好的分离效果和适中的价格,在过去几十年中被广泛应用。
*高使用温度:相对较低,通常为70-120°C。这是因为PEG-400分子量较小,蒸气压较高,温度过高会导致固定液流失严重,基线不稳,柱寿命缩短。
应用范围:特别适用于分离极性化合物和可形成氢键的化合物。
Polyethylene glycol 400 packed column
A gas chromatography column made by coating PEG-400 as a stationary phase on an inert solid carrier and filling it in a metal or glass tube.
Core components
A complete polyethylene glycol-400 packed column consists of three parts:
Column tube: usually made of stainless steel or glass material, with a length of 1-3 meters and an inner diameter of 2-4 millimeters.
Carrier: A chemically inert, porous solid particle used to carry a fixative. Commonly used ones include:
Chromosorb W: a white diatomaceous earth carrier with good inertness, suitable for polar fixatives and analysis of polar samples.
Chromosorb P: a red diatomaceous earth carrier with slightly stronger adsorption properties.
Glass microspheres: Non diatomaceous earth carrier, with extremely low adsorption capacity.
Fixed phase: Polyethylene glycol-400.
PEG-400 is a polyethylene glycol with an average molecular weight of 400, which is liquid at room temperature.
It is a polar stationary phase, and its separation mechanism is mainly based on hydrogen bonding forces and dipole dipole interactions between the substance and the stationary phase.
Name: Gas Chromatography Column
Specification: Polyethylene glycol 400:6201 support (60-80 mesh) 20:80
Model: PEG-400/6201; 3M*3MM
Number: 20251112001
Zui high temperature: 100 ° C
Applications: acids, aldehydes, alcohols, esters, benzene derivatives, fusel oils
Suitable for:
Agilent 490 online/portable, 48905890689088608890
Shimadzu GC-14C, GC-2010, GC-2014, GC-2030
Thermo Fisher Scientific 1310130016101600
Varian 3800 Series
Brooke PE580590680690
Panno A90, Fuli GC9790, Huaai, Tianrui, Tianmei, GC7900, Chuanyi, Beifen Ruili, Dongxi Electronics, Lunan Ruihong, Jiedao/Kexiao
The main features of the PEG400 packed column developed by Haohan Chromatography are:
Polarity: Belongs to the fixed phase of medium strong polarity.
Universal polarity column: Due to its excellent separation effect and moderate price, it has been widely used in the past few decades.
Maximum operating temperature: relatively low, usually 70-120 ° C. This is because PEG-400 has a small molecular weight and high vapor pressure. Excessive temperature can cause severe loss of fixative, unstable baseline, and shortened column life.
Application scope: Especially suitable for separating polar compounds and compounds that can form hydrogen bonds.